Method for fabricating multi-layer optical films

ABSTRACT

A method for fabricating multiple layer interference optical films by ion beam sputtering, said films being used for mirrors in a ring laser apparatus. An ion beam strikes a target material obliquely, dislodging molecules of the target so that they can be deposited on a surface serving as a base for a multiple layer interference coating. The thickness of the coating is monitored so that the proper thickness of a given layer can be optimized to obtain the type of reflectance desired for a given light wave length. The surface to be coated is rotated during the deposition of the layer of target material. A stack of layers of alternating indices of refraction comprises the optical interference film. The coating process occurs inside of a vacuum chamber where the partial pressures of the gases are carefully controlled to insure the proper ion beam intensity and optimum stoichiometry of the deposited optical films. Prior to beginning the deposition of optical films, the ceramic substrate comprising the mirror base is bombarded by the ion beam at an oblique angle to remove surface anomalies and clean it.

BACKGROUND OF THE INVENTION

The present invention relates to a sputtering apparatus and method forfabricating durable dielectric thin film optical coatings such as thosecommonly used in quarter wave stacks for laser mirrors.

In ring laser gyroscopes, one of the principal obstacles to overcome isthe phenomena of frequency synchronization or lock-in between theoppositely propagating laser waves within the ring laser cavity. Thephenomena of lock-in is fully explained in the test "Laser Applications"edited by Mote Ross, Academic Press, New York, 1971, in the chapterentitled, "Laser Gyroscope," at pages 148-153. The principal cause oflock-in is the phenomena of back scatter which occurs at the reflectingsurfaces of the quarter wave stacks in the mirrors in the laser path.Back scatter is caused by anamolies and surface roughness in thereflective surfaces of the various layers of the quarter wave stacks.

Quarter wave stacks and their design are explained in detail in theMilitary Standardization Handbook entitled "Optical Design,"MIL-HDBK-141, Oct. 5, 1962. Briefly, each layer or thin film dielectriccoating in a quarter wave stack has a thickness of about one quarter ofa wavelength of the light which it is designed to reflect. The number oflayers which comprise the quarter wave stack depends on the degree ofdesired reflectance and the differences in refractive indices of thelayers. To increase reflectance, the number of layers and/or thedifferences in refractive indices may be increased. For mirrors used inring lasers, the quarter wave stacks generally consist of 17 to 25quarter wave thin film optical layers deposited on a substrate. Eachlayer is typically from 500 to 800 Angstroms thick. The layers alternatebetween a material of high index of refraction and a material of lowindex of refraction. Typically, the high index material is tantalumpentoxide (Ta₂ O₅) or titanium dioxide (TiO₂) and the low index materialis silicon dioxide (SiO₂, i.e., quartz).

In order to minimize back scatter and absorption losses in the quarterwave stack, it is desirable to obtain amorphous coatings which are freeof voids and which approach the density and refractive index of the bulkmaterial from which the coatings are obtained. The goal is to get amolecule-by-molecule deposition of the coating and avoid a crystallinestructure. Also, it is desired to avoid the formation of suboxides whichmay result from the lack of sufficient oxygen in the chamber.

Up until now the principal method of fabricating quarter wave stacks forring laser mirrors has been to use an electron beam evaporationtechnique. A substrate on which a reflective stack is to be coated islocated inside of a vacuum chamber with a sample of the bulk or targetmaterial which is to be deposited. An electron beam focussed on thesample material causes localized heating of the material to a pointwhere molecules are evaporated off. These molecules then condense on theother surfaces located in the interior of the vacuum chamber, includingthe substrate which is being coated.

An electron beam has been used because of its capability of transferringsufficient thermal energy to a localized area of the target material.The kinetic energy of the electrons in the beam are converted to thermalenergy when the beam is directed at the evaporate material. Molecules ofthe target material are heated to the point where molecules or groups ofmolecules are boiled off. This process of electron beam evaporation as ameans of coating is thoroughly explained in the text, "Physical VaporDeposition," distributed by Airco Temescal, 2850 7th Street, Berkeley,Calif., 1976.

One of the principal problems encountered in the electron beamevaporation technique is to coat layers of the quarter wave stack sothat they approach the density of the bulk material from which theycome. With this process, molecules of the target material condense onthe substrate in such a manner that voids are left between them. Theresulting coating is less dense than the bulk, which results in adifference in the layer's index of refraction. Because of theunpredictability of the final density, it is difficult to determine andto control the refractive indices of the stack.

Another problem with the electron beam technique has to do with theelectron beam encountering impurities or air pockets in the targetmaterial. The high heat concentration results in small explosions whichthrow out larger chunks of multiple molecules and impurities whichcondense in the layer. These impurities increase back scatter andabsorption in the laser mirror.

With the electron beam evaporation technique, parameters includingtemperature of the substrate, partial pressure of oxygen in the chamber,rate of deposition, and preparation of the target material are varied inattempts to control and improve the oxidation state, packing density,and degree of amorphousness of the stack. Generally, determining theproper variations and controlling them is very difficult. Typically,temperature of the substrate must be maintained at about 300 degreesCentrigrade in order to get a high density coating which is relativelyfree of voids and sufficiently amorphous. Until now, the electron beamevaporation technique has been refined to the point where it canconsistently produce laser mirrors with losses from absorption and backscatter in the range of 0.1 percent.

Radio frequency (RF) sputtering has been tried in the past as a possiblemeans of depositing thin films for laser mirrors. RF sputtering isexplained in Physical Vapor Deposition, supra, at pages 106 to 108.Briefly, the method employes two plates with argon gas between them. Onone plate is mounted a substrate to be coated and on the other is thetarget material. A high frequency, high voltage, a-c field between theplates ionizes the gas atoms causing them to move back and forthstriking the target and knocking off molecules which are then depositedon the substrate.

Coatings made in this fashion have tended to be crystaline. Further, theprocess causes the coating to agglomerate (i.e., have a high surfaceroughness) and substrate temperature is nearly impossible to controlaccurately. RF sputtering is presently used for commercial applications,but generally not for specialized thin optical film applications.

SUMMARY OF THE INVENTION

It is the purpose of this invention to produce high quality quarter wavestacks for laser mirrors. Such mirrors have greatly increased packingdensities and improved amorphous states in the individual layers, andimpurities and surface anomalies are substantially reduced. This isaccomplished by employing the technique of ion beam reactive sputteringto produce the dielectric coatings which make up the quarter wave stackmirrors. An important aspect of this invention is that the ion beamsputtering bombards a target material with ions. These ions strike thetarget with high momentum and break away individual molecules of thetarget material. The target molecules are then deposited on thesubstrate which comprises the base for the laser mirror. This techniqueresults in a molecule-by-molecule deposition on the substrate for animproved amorphous coating and increased packing density. Also, themolecules adhere better to the substrate due to higher molecularvelocities associated with ion beam sputtering.

Another important aspect of the invention is that it is an essentiallycold process whereby the substrates being coated need not be maintainedat high temperatures to achieve amorphous states and acceptable packingdensity levels. Further, because it is a cold process whereby ions breakthe molecules of the target material loose rather than boiling them awaythrough localized applications of high energy, air voids and impuritiesin the target material do not cause small explosions with attendantbreaking away of larger chunks of material which may deposit on thesubstrate. This in turn greatly reduces impurities and anomalies in thequarter wave stack layers.

Another important aspect of the invention is the presence of oxygen inthe vacuum chamber where the substrate is being coated. The amount ofoxygen flow available for oxidation of the molecules in the layers mustbe closely controlled to minimize the formation of suboxides which wouldotherwise constitute absorbtion impurities in the layers or coatings.This control, together with other features including the cold processaspect, greatly simplifies the process of coating laser mirrors andmakes the final densities and refractive indices much more predictable.

A further aspect of the invention is the ability to bombard the basesubstrate with ions prior to the beginning of the deposition of the thinfilms. This bombarding of the substrate surface removes surfaceanomalies and also cleans the substrate surface to remove imperfectionsand impurities which might otherwise be detrimental to the mirror'sreflectivity.

At present, the ion beam deposition method is capable of consistentlyproducing quarter wave stack mirrors for lasers with losses in the rangeof 0.01 percent. This represents a significant improvement in thetechnology relating to thin film depositions, and particularly to thefabrication of quarter wave stacks for laser mirrors.

Other objects, features, and improvements accomplished by this inventionwill become apparent from the study of the figures and the detaileddescription of the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a partial cross section front view showing the inside of avacuum chamber with the various apparatus necessary to accomplish ionbeam sputtering for making interference optical films.

FIG. 2 shows a side view cross section of the vacuum chamber shown inFIG. 1 which illustrates how the turret on which the target materialsare mounted fits and operates with the vacuum chamber.

FIG. 3 is a cross sectional view of the apparatus used to manipulate androtate the substrate mounting surface inside of the vacuum chamber withcontrols outside of the chamber.

DETAILED DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a cross sectional view of a vacuum chamber apparatus usedfor fabricating interference optical films by ion beam sputtering. Thevacuum chamber 2 contains argon at about 1.5×10⁻⁴ torr. Argon enters thechamber through tube 3, the argon being released in the chamber in thearea of the ion beam gun 4.

Oxygen is also present inside of the chamber to insure the properstoichimetry of the layers deposited in the optical mirrors. The partialpressure of oxygen depends on whether the target material being coatedhas a high or low index of refraction. For high index materials, thepartial pressure of oxygen is about 5×10⁻⁵ torr, while it is about3×10⁻⁶ for low index materials.

The oxygen enters the chamber through tube 36. Because the partialpressure of oxygen is much less than the partial pressure of argon inthe chamber, a special apparatus has been devised for measuring only thepressure of the oxygen. A pressure sensor 7 with a voltage output sensesthe pressure in the oxygen line 5. The pressure sensor output istransferred to a servo-valve controller 9, such as a Granville Phillipsservo-valve controller. The servo valve controller opens and closesservo valve 11 to maintain the oxygen in line 5 at a pre-determinedconstant pressure. Oxygen is fed to servo-valve 11 through tube 13. Thelocation of the pressure sensor 7 is far enough away from the chamberthat it effectively only measures the pressure of oxygen being fed tothe chamber, rather than the argon in the chamber.

Another possible way to control the amount of oxygen is to introduce gasmixed in the proper ratio through tube 3.

The ion beam gum 4 is a commercially available ion omitting aparatusgenerally known in the art as a Kauffman type ion beam gun. The gun'scathode 6 is a thermonic emitter, i.e., it emits electrons by passing anelectric current through it which heats the wire. The cathode 6 emitselectrons which are accelerated towards the anode 8. The electrons beingaccelerated from the cathode to the anode strike argon atoms and in sodoing dislodge electrons from the argon. The results are positivelycharged argon ions which are accelerated away from the anode and towardsthe grids 12 and 14. Permanent bar magnets 10 attached to the anodeintroduce a magnetic field into the area between the cathode and theanode which cause the electrons traveling towards the anode to spiral.This spiral motion effectively increases the distance which theelectrons travel in reaching the anode and thereby increases number ofcollisions between electrons and argon atoms.

In the space between the cathode 6 and anode 8, the electrons and argonions create a glowing plasma. This plasma is at a high negativepotential with the lower grid 14 being at about ground potential. Thedifference in voltage between the two grids 12 and 14 is from 500 to1500 volts so that the argon ions passing between the two grids areaccelerated at a high velocity away from the plasma and out of the gun.These ions constitute an ion beam.

Metal containers 16 contain electric wires that are maintained while hotso that they emit electrons. These emitted electrons are introduced intothe beam through pin holes 17 in the container. This is to maintain thecharge balance of the ion beam.

The beam intensity developed is about 100 milliamps and 1000 volts. Beamintensity depends upon the cathode current, voltage between the anodeand cathode, and the partial pressures of the gases inside of thechamber 2. Presently, cathode current is about 20 amps while the voltagebetween the anode and cathode ranges from 40 to 60 volts. The argonpartial pressure is 1.5×10⁻⁴ torr. In addition, oxygen is introducedthrough the chamber with a partial pressure of about 5×10⁻⁵ torr or3×10⁻⁶ torr, depending on whether high index of refraction materials orlow index of refraction materials respectively are being deposited on asubstrate.

A water cooled four target turret 18 is provided. A target is the basepiece of material at which the ion beam is aimed so that atoms of thetarget material are dislodged and are coated onto a substrate. Targetsare soldered to backing plates, and the surfaces A, B, C and D of theturret 18 are provided for mounting these backing plates. A separatebacking plate may be mounted to each surface.

During the sputtering process, the targets often become too hot. Sincethe sputtering rate is temperature dependent, the higher the temperatureof the target, the higher the rate of the deposition onto the substratebeing coated. Therefore, in order to control the temperature of thetargets, standard practice in sputtering is to have water lines insideof the turret 18 with circulating water to cool the target. How theturret functions and how water is circulated will become more apparentupon consideration of FIG. 2.

In the configuration shown in FIG. 1, the ion beam emanating from thegun 4 is directed at surface A of the turret, as indicated by thearrows. Atoms of the target material are dislodged and are coated ontothe surfaces inside of the chamber 2. A ceramic substrate 20 comprises abase on which dielectric coatings are to be deposited. This substrate ismounted on the disk at the end of the shaft 22. The substrate forms thebase for the ring laser mirror and it is located near the target insideof the chamber so that it will be in the main stream of the atomsdislodged from the target 18. The shaft 22 has a joint 24 so that theangle of the substrate may be varied by moving the bar linkage 26 in andout of the chamber. The bar linkage is allowed to slide in and out ofthe vacuum chamber by use of a hermetic seal which is commonly availableand well known in the art. Further, by sliding the shaft 22 further intothe chamber and adjusting the bar linkage accordingly, the substrate 20may be placed directly in the stream of the ion beam and tiled such thatthe beam strikes the surface of the substrate. This position isillustrated by dashed lines 28.

A sleeve 30 is provided to connect the bar linkage 26 to the shaft 22.This sleeve permits the shaft to rotate while being supported by the barlinkage 26. During the coating process, the shaft is rotated at about 60revolutions per minute. The apparatus for varying the position of theshaft and rotating it inside of the chamber are further illustrated indetail in FIG. 3.

A crystal quartz monitor 32 is provided inside the chamber near thesubstrate to monitor the thickness of a coating on the substrate. Themonitor 32 measures thickness by measuring the increase in mass on thequartz due to the coating on its surface. The quartz crystal isconnected to an oscillator circuit through wires 34. As the mass of thecoating increases, the natural frequency of the oscillation circuitdecreases. Frequency of the oscillation circuit is calibrated to yield areading corresponding to the thickness of the coating deposited on thequartz. The thickness of the coating on the quartz corresponds to thethickness of the coating on the substrate 20. Such monitors arecommercially available and are well known in the art.

FIG. 2 shows a side view of the vacuum chamber 2. As illustrated, thefour sided water cooled turret 18 is supported along a shaft 38 and by ahorizontal bar 40. A vertical bar 42 is attached by bearings 44 to thecenter of the turret and is connected to the horizontal bar 40 through aroller bearing 46. The arrangement as shown allows the horizontal bar 40to provide support to the turret 18 while the shaft 38 is allowed torotate the turret and slide in and out of the chamber while bar 40supports the turret. Flexible tubes 48 enter the hollow shaft 38 outsideof the chamber and provide circulating water to the mounting surfaces ofthe turret. The metal tube 50, fixedly attached to the side of thechamber, provides housing and support for the hollow shaft 38. An "O"ring seal 52 is provided as a seal between the housing tube 50 and theshaft 38. Outside handles 54 are fixedly attached to the shaft 38 andare supported at one end on ball bearings 56. The position of thesehandles relative to the index 58 provides information to the operatorregarding the angular position of the turret inside of the chamber.

Referring to FIG. 3, an apparatus is provided whereby the substratemounted on the end of the shaft 22 can be rotated inside of the vacuumchamber 2. Bucking magnets 60 and 62 are clamped between a circular ring64 and a pulley 66. The ring, bucking magnets, and pulley are fastenedtogether by bolts 65 to form a bucking magnet assembly. Ball bearings 68and 70 attach the bucking magnet assembly to the supporting tube housing72. This housing 72 is fixedly attached to the outside of the chamber.The shaft 22 is secured inside of the housing 72 by ball bearings 74 and76. The inner races of bearings 74 and 76 are attached to the shaft 22while the outer races are attached to rollers 78. The roller 78 providessupport to the shaft such that it does not touch the sides of thetubular housing 72 as the shaft 22 slides in an out of the chamber.Bearings 74 and 76 permit the shaft 22 to rotate while the rollers andtube housing remain stationary.

As the bucking magnets and pulley rotate around the tubular shaft 72,the magnetic field from magnets 60 and 62 rotates and exerts an angularforce on an armature 80 which is fixedly attached to the shaft 22. Thistype of armature is a piece of highly permeable iron and is well knownin the art. As the bucking magnet and pulley rotate, the substratelocated inside of the chamber also rotates. An electric motor 82 isconnected to the pulley by way of a "V" belt 84 to provide a constantdrive to the shaft 22. Shaft 86 is connected to the inner race of ballbearing set 88 while the outer race is connected to the outer race ofball bearing set 76. This arrangement allows shaft 22 to rotate freelywhile shaft 86 remains stationary. However, as shaft 86 slides in andout of the tubular housing 72, shaft 22 is constrained to move with it.A threaded cap 90 secures an "O" ring seal 92 between the tubularhousing 72 and the shaft 86 seals the vacuum chamber.

The apparatus described in the FIGS. 1, 2 and 3 is suitable for ion beamsputtering of many types. The process described here will be fordeposition of thin film layers onto ceramic substrates to form a seriesor stack of quarter wave layers to reflect laser beams in ring lasergyroscopes. However, the process is not necessarily limited to thefabrication ring laser mirrors.

Referring again to FIG. 1, a ceramic substrate 20 mounted to the end ofshaft 22 is positioned as shown by dashed lines 28 in the ion beamstream. The ion beam bombarding the surface of the substrate at an anglecleans it to remove impurities located on the surface and removes roughspots. This provides a cleaner and smoother surface and allows for abetter thin film coating. The substrate is then retracted to theposition shown in FIG. 1 and the target located on mounting surface A ofthe turret 18 is bombarded by the ion beam. Atoms which are dislodgedfrom the target are coated on the exposed surfaces, including thesubstrate, located inside of the chamber 2.

A glass shield 102 is provided inside of the chamber. The shield isrotated into the position shown in FIG. 1 by the apparatus 103 locatedoutside of the chamber which allows the vacuum chamber to remain sealedwhile allowing the shaft 104 which is attached to the shield to berotated.

Targets that have been exposed to the atmosphere may have contaminantsfrom handling or oxidation and other corrosion on their surfaces. Priorto coating a thin film, the targets are cleaned inside of the chamber bybombarding them with the ion beam and removing the oxidation andcontamination. During this cleaning, the bar linkage 26 and the shaft 22are manipulated such that the substrate 20 is positioned behind theglass shield 102. In this manner, contaminants and oxidation removedfrom the targets are prevented from depositing on the substrate surface.

A high index of refraction material, such as titanium dioxide, is thetarget material on surface A of the turret 18. As shown in FIG. 1, theion beam strikes the target on surface A obliquely and dislodges atomsof the target material. Note that the substrate is positioned inside ofthe chamber in the main path of the target molecules which have beendislodged by the ion beam. The titanium dioxide target is bombarded bythe ion beam until the layer deposited has an optical thickness of 1/4of a wave length of a laser beam. Because different laser beams may havedifferent wave lengths, the proper thickness of the quarter wave layermay vary depending on particular design parameters. Proper layerthickness is calculated by the formula below: ##EQU1##

A low index of refraction target material such as silicon dioxide isattached to surface C of the turret. When the high index of refractionquarter wave layer is complete, the turret is rotated 180° and the ionbeam obliquely bombards the target on surface C to deposit a low indexof refraction quarter wave layer. Typically, a silicon dioxide layer isabout 1,000 Angstroms thick, while a titanium dioxide layer is about 700Angstroms thick.

This procedure is repeated until a stack of alternating layers of highand low index of refraction materials is deposited. The number of layersdeposited depends on the differences in the indices of refraction of thematerials and the amount of desired reflectance. Suitable high index ofrefraction materials are those having an index of refraction greaterthan 2.0. Low index materials generally have an index of less than 1.5.The materials discussed above, titanium dioxide and silicon dioxide,have indices of refraction of about 2.4 and 1.46 respectively.

Titanium dioxide silicon/dioxide mirrors typically have 21 alternatinglayers for maximum reflectance. Where mirrors are required which allow0.05 to 0.01 percent transmittance, about 19 alternating layers areused. If the difference in index of refraction is less between layermaterials, more layers are required to achieve the same reflectance.

Incidentally, the substrate forming the base of the ring laser mirror isgenerally an ultra low expansion ceramic material such as Zero-Dur,manufactured by Shott Glass, or Cervit, manufactured by Owens-Illinois.Other materials may be substituted for the substrate and for thealternating layers of high and low index of refraction materials usedfor targets and still be within the scope and intent of this invention.

What is claimed is:
 1. A method of fabricating multiple layer opticalfilms.Iadd., said multiple layer optical films comprising optical layershaving different indices of refraction .Iaddend.comprising:bombardingtargets obliquely with an ion beam .Iadd.produced by or derived from aKaufman-type ion beam source .Iaddend.in a vacuum chamber to sputterdeposit a plurality of optical film layers on a base; controlling theatmosphere inside .[.of.]. the vacuum chamber to provide sufficient gasto sustain the ion beam and the proper amount of oxygen to accomplishproper stoichiometry of the thin films; and depositing multiple layersof different materials on said base by varying the targets beingbombarded by the ion beam; and continuously rotating said base duringthe deposition of said multiple optical layers. .[.2. The methoddescribed in claim 1 wherein said multiple layer films comprise opticallayers having different indices of refraction..].
 3. The methoddescribed in claim 1 further comprising bombarding said base obliquelywith an ion beam prior to bombarding said targets to clean said base andto remove surface anomalies.
 4. The method described in claim 1 whereinoptical layers with indices of refraction greater than 2.0 and opticallayers with indices of refraction less than 1.5 are deposited inalternating layers.
 5. The method described in claim 4 wherein saidoptical layers with indices of refraction greater than 2.0 are titaniumdioxide.
 6. The method described in claim 4 wherein said optical layerswith indices of refraction less than 1.5 are silicon dioxide.
 7. Themethod described in claim 4 wherein said alternating layers are quarterwave layers.
 8. The method described in claim 1 wherein the targetsbeing bombarded by the ion beam are cooled to prevent excessive heatbuild-up and control sputtering rate.
 9. The method described in claim 1wherein said base is a low expansion ceramic substrate. .Iadd.10. Themethod described in claim 1 wherein said base and said multiple layeroptical films form a mirror. .Iaddend. .Iadd.11. The method of claim 10wherein said mirror is a ring laser gyroscope mirror. .Iaddend..Iadd.12. The method of claim 11 wherein said ring laser gyroscopemirror has alternating layers of silicon dioxide and titanium dioxide..Iaddend. .Iadd.13. The method of claim 10 wherein said mirror is a ringlaser gyroscope mirror, and said method further comprises controllingthe method parameters so that each of said optical films containsreduced impurities or surface anomalies of the kind that cause backscatter and absorption in laser mirrors, and is free of voids. .Iaddend..Iadd.14. The method described in claim 1 wherein said base and saidmultiple layer optical film form a quarter wave stack mirror for usewith a laser, said mirror having at least two optical layers withsubstantially different indices of refraction. .Iaddend. .Iadd.15. Themethod of claim 14 wherein said mirror is a ring laser gyroscope mirror..Iaddend. .Iadd.16. The method of claim 15 wherein said ring lasergyroscope mirror has alternating layers of silicon dioxide and titaniumdioxide. .Iaddend. .Iadd.17. The method of claim 14 wherein said mirroris a ring laser gyroscope mirror, and wherein said method furthercomprises controlling the method parameters so that each of said opticalfilms has reduced impurities or surface anomalies of the kind that causeback scatter and absorption in laser mirrors, and is free of voids..Iaddend. .Iadd.18. A method of fabricating multiple layer opticalfilms, said multiple layer optical films comprising at least two opticallayers having different indices of refraction, in alternating layers,comprising:bombarding at least two targets comprising materials havingdifferent indices of refraction obliquely with an ion beam produced byor derived from Kaufman-type ion beam source in a vacuum chamber tosputter deposit a plurality of optical film layers comprising saidmaterials in alternating layers on a base; controlling the atmosphereinside of the vacuum chamber to provide sufficient gas to sustain theion beam and the proper amount of oxygen to accomplish properstoichiometry of the thin films; depositing multiple layers of saidmaterials having different indices of refraction on said base by varyingthe targets being bombarded by the ion beam; and continuously rotatingsaid base during the deposition of said multiple optical layers..Iaddend. .Iadd.19. The method of claim 1 or claim 3 or claim 4 or claim5 or claim 6 or claim 7 or claim 8 or claim 9 or claim 10 or claim 12 orclaim 13 further comprising controlling the method parameters so thateach of said optical films has a predictable, predetermined density andrefractive index, reduced impurities or surface anomalies of the kindthat cause back scatter and absorption in laser mirrors, is amorphous,and is free of voids. .Iaddend. .Iadd.20. The method of claim 1 or claim3 or claim 4 or claim 5 or claim 6 or claim 7 or claim 8 or claim 9 orclaim 14 or claim 18 further comprising controlling the methodparameters so that each of said optical films has a predictable,predetermined density and refractive index, and reduced impurities orsurface anomalies of the kind that cause back scatter and absorption inlaser mirrors. .Iaddend. .Iadd.21. The method of claim 1 or claim 3 orclaim 4 or claim 5 or claim 6 or claim 7 or claim 8 or claim 9 or claim14 or claim 18 further comprising controlling the method parameters sothat each of said optical films has a predictable, predetermined densityand refractive index, reduced impurities or surface anomalies of thekind that cause back scatter and absorption in laser mirrors and isamorphous. .Iaddend. .Iadd.22. The method of claim 1 or claim 3 or claim4 or claim 5 or claim 6 or claim 7 or claim 8 or claim 9 or claim 14 orclaim 18 further comprising controlling the method parameters so thateach of said optical films has a predictable, predetermined density andrefractive index, reduced impurities or surface anomalies of the kindthat cause back scatter and absorption in laser mirrors and is free ofvoids. .Iaddend.